Let {σj} be the three Pauli matrices. {iσj} serve to generate a Clifford algebra C over the reals. Let γj = iσj for j = 1, 2, 3. I emphasize that the algebra is over the reals despite the appearance of i in the expressions. i is not a scalar here; i is not a member of K or even C.
Let me say the same thing very pedantically in order to alleviate some confusion. Let MC2 be the vector space of 2 by 2 complex matrices. Consider the smallest subspace C of MC2 which includes each {σj} for j = 1, 2, 3, and is closed under multiplication, addition and scalar multiplication by reals. C is isomorphic φ to a real rank 3 Clifford algebra where φ(σj) = γj for j = 0, 1, 2, 3.
P = {Σj ajσj | for j = 0, 1, 2, 3; aj is real} where σ0 = I.
There is an associative algebra P generated by {I, σ1, σ2, σ3} which is strategic to quantum mechanics. P is the even part of C. C includes reflections; P does not. Note that V (the span of {iσj}) is not in P; only Hermitian matrices belong to P. You might get away with saying that iσ1 represents a reflection in the x direction but I doubt that this is warranted.
To be a Clifford algebra it suffices that γjγj = −1 and γjγk + γkγj = 0 when j≠k. These are all satisfied. The corresponding Clifford group provides the rigid rotations of R3.
Perhaps an isomorphism table will help;
Pauli | Clifford |
0I | 0 |
I | 1 |
iσj | γj |
iI | γ1γ2γ3(=k) |
σj | −kγj |
σ1 | γ3γ2 |
σ2 | γ1γ3 |
σ3 | γ2γ1 |
This is a twisted isomorphism! Perhaps there is a better one. The two red entries are not even in the space P.
I subsequently found section II of this. This paper uses the rule γiγj + γjγi = 4δij for the algebra Cl3,0. This is contrary to all the other papers I have seen where γ1γ1 = −1. His rule works for what I would call Cl0,3 except for a factor of two.
I want to do the same thing with the Dirac matrices but I can’t improve on this page which shows that the ‘gamma matrices’ already form a Clifford algebra for a vector space with quadratic form with signature (+ − − −). Even the convention of naming the basis elements γ carries over. Here are further gropings for Dirac.
P.S.
The original Clifford algebras require γjγj = −1 but Minkowski space has a non-definite signature for the metric and describing boosts for that space requires a ‘Clifford algebra’ where γjγj = ±1, depending on j. The definition has thus been stretched so that γjγj = 1 yields a new sort of Clifford algebra. I don’t know whether Clifford considered it. That algebra also yields the orthogonal rotations of R3.